P-Card (purchasing card) reports are usually separate from an Expense Report. It sounds like your company might use a different module for Pcards. If you check the box to the left of the expense, and click the "Move" button, does it give you the option to start a new statement report? Since this is the first use of your card, you may have to start a report this way. But, in the future, Concur will start the report for you.
If you do not have this option, you may need to reach out to your Concur Administrator at your company to make sure you have been assigned the correct role and that your card has been mapped to your Pcard program.
Best,
